1673-159X

CN 51-1686/N

掺SAP对混凝土抗冻性的影响及其作用机制探讨

Effect and Mechanism of SAP on Freezing Resistance of Concrete

  • 摘要: 高吸水性树脂(superabsorbent polymers,SAP)具有良好的保水和储水性能,是混凝土内养护和强化抗冻较好的性能材料之一。本文阐述了SAP增强混凝土抗冻性能的机制,同时总结分析了不同参数对混凝土抗冻性能的影响。分析表明:SAP的释水行为主要分为渗透压控制阶段和湿度控制阶段,释水后的SAP在混凝土中能形成宏观孔隙和凝胶孔隙,提高混凝土抗冻性能;SAP的掺量、粒径以及掺入方式等因素均会影响混凝土的抗冻性能,最佳掺量和粒径应分别根据SAP的吸水性和气孔间距系数而定,干燥掺入方式更有利于提升混凝土的抗冻性能。针对目前存在的问题,提出后续可研究不同水胶比下掺SAP对混凝土抗冻性能的影响,建立不同水胶比下SAP孔隙大小与混凝土抗冻性能的相关模型。

     

    Abstract: Superabsorbent polymers (SAP) exhibit excellent water retention and storage properties, and is one of the preferred materials for internal curing and enhancing the freeze-thaw resistance of concrete.This paper explores the mechanism by which SAP enhances this property and reviews the effects of various parameters on concrete freeze-thaw resistance. The results indicate that the water release behavior of SAP primarily consists of an osmotic pressure-controlled stage and a humidity-controlled stage. Post water release, SAP forms macro pores and gel pores within the concrete, thereby enhancing its freeze-thaw resistance. Factors such as the dosage, particle size, and mixing method of SAP all influence the freeze-thaw resistance of concrete. The optimal dosage and particle size should be determined based on the water absorbency of SAP and the air-void spacing factor, respectively, with dry mixing being more beneficial for enhancing the freeze-thaw resistance of concrete. In view of the existing problems, it is suggested that the influence of SAP on the freezing resistance of concrete under different water-binder ratio can be studied in the future, establish a correlation model between SAP pore size and frost resistance of concrete under different water-to-binder ratios.

     

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