1673-159X

CN 51-1686/N

QPQ工艺对低碳钢显微结构及极化性能的影响

Influence of QPQ Salt-bath Nitriding and Post-oxidation Process on Microst-ructure and Electrochemical Polarization Properties of Low Carbon Steel

  • 摘要: 用QPQ盐浴复合处理技术对低碳钢进行表面改性处理,对处理后的低碳钢表面进行系统表征。结果表明:QPQ氮化处理后低碳钢试样表面从外至内由Fe3N/Fe24N10/FeN0.0939组成,氧化处理后,试样表面从外至内的组成物变成了Fe3O4/Fe2N/α-Fe,氧化处理使外层氮化层由Fe3N转变成Fe3O4/Fe2N,内层氮化层由Fe24N10/FeN0.0939转变成α-Fe;氧化处理后,分别在外层氮化层和内层氮化层上出现大量的显微裂纹和孔状结构;与只进行过氮化处理的试样相比,氧化处理后试样的表面硬度降低了50~100 HV0.025。通过极化曲线可以看出,与氮化试样相比氧化处理后腐蚀电流密度下降了0.055 μA.cm-2,腐蚀电位也降低了79 mV。这表明氧化处理能有效提升试样的耐腐蚀能力,而氧化过程中产生的表面缺陷可能导致了腐蚀电位下降。

     

    Abstract: Low carbon steel was surface modified by the quench-polish-quench salt bath treatment process (QPQ). The modified surface was systematically characterized. The results reveal that the nitrided sample surface consists of Fe3N/Fe24N10/FeN0.0939, while the post-oxidized sample surface consists of Fe3O4/Fe2N/α-Fe. The Fe3N in the outer-layer and Fe24N10/FeN0.0939 in the sub-layer were transformed as Fe3O4/Fe2N and α-Fe, respectively, after conducting post-oxidation process. After post-oxidizing, many cracks and pores were observed on the outer-layer and sub-layer. The hardness profile of post-oxidized sample decreased about 50~100 HV0.025 with comparison to nitrided sample. The polarization curves results reveal that the corrosion current density (icorr) of post-oxidized sample decreased about 0.055 μA.cm-2 with comparison to nitrided sample, indicating an improvement of corrosion resistance. However, the corrosion potential (Ecorr) decreased about 79 mV, which may be caused by the cracks and pores formed on the compound layer by post-oxidizing process.

     

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