Ag对Sn-Bi无铅钎料压入蠕变性能及显微组织的影响
Effect of Ag on Indentation Creep Property and Microstructure of Sn-Bi Solder
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摘要: 对Sn-4.8Bi和Sn-4.8Bi-3.4Ag合金进行了压入蠕变试验, 得到两种合金的蠕变曲线, 分析了压入蠕变随载荷和温度的变化规律。利用X射线衍射(XRD)和扫描电镜(SEM)分别对合金的物相组成和蠕变前后的微观显微组织进行分析。结果表明: 添加Ag元素可提高Sn-Bi合金钎料的抗蠕变性能。蠕变前, Sn-Bi合金中析出相为独立存在的颗粒状Bi, 加入Ag后有条状和块状的Ag3Sn析出, 且Bi析出减少; 蠕变后, Sn-Bi合金中析出的Bi相变得细小并弥散分部于基体中, 添加Ag后的合金中条状析出相变得细小, 块状析出相变得粗大, 但Bi相析出数量进一步减少。Abstract: Creep curves were obtained by indentation creep test for Sn-4.8Bi and Sn-4.8Bi-3.4Ag alloy, and the changing rule of indentation creep with load and temperature was summarized.The chemical compositions of precipitated phases and the micro-structures before creep and after creep were analyzed by X-ray diffractometry(XRD) and scanning electron microscope(SEM).The results show that the creep resistance of Sn-Bi solder is improved by adding Ag.The precipitated phase of Sn-Bi alloy is Biby contrasting the precipitated phases Ag3Sn and decreased Bi in Sn-Bi-Ag alloy before creep.The granular phase Bi is fine and forms diffuse distribution in the matrix during creep deformation in Sn-Bi solder.The stripy phase Ag3Sn is fine, the massive phase is coarse, but phase Bi further decreases in Sn-Bi-Ag solder after creep.The stripy phase and massive phase Ag3Sn containing Ag element and fined Bi play an important role for the improvement of the creep resistance of Sn-Bi-Ag alloys.