1673-159X

CN 51-1686/N

成核剂对iPP晶体形态、结晶度与力学性能的影响

Study on the Effect of β Nucleating Agent on the Mechanical Properties of Polypropylene

  • 摘要: 利用偏光显微镜(PLM)和广角X射线衍射法(XRD)对β成核聚丙烯的结晶行为的表征,以及拉伸性能和冲击性能测试研究的结果表明: β成核剂的加入使聚丙烯中有β晶型出现,随着成核剂加入量的增加,β成核改性iPP的结晶度和晶体尺寸分别增大和减小,β成核剂为0.1%时成核改性iPP的冲击强度达到最佳,β成核剂加入量高于0.1%时,成核改性iPP的冲击强度呈降低趋势,拉伸强度、断裂强度和刚度则呈增大趋势。

     

    Abstract: Crystallization of β nucleated polypropylene was characterized by using the polarized optical microscopy (PLM) and wide-angle X-ray diffraction (XRD) and the research results of the tensile and impact properties indicate that β nucleating agent significantly introduced β-PP crystal and with the increase in β nucleating agent β-PP crystallinity of β nucleated PP increased, so that its impact strength achieved the highest value when there was 0.1% of β nucleating agent in iPP. While the content of β nucleating agent was over 0.1% the impact strength as well as the tensile and fracture strength and Young's modulus of iPP appeared decrease and increase respectively.

     

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