1673-159X

CN 51-1686/N

势垒过滤对热电输运影响的研究现状

Review on the Thermoelectric Transport by Potential Barrier Filtering

  • 摘要: 材料中的各种界面及缺陷将形成一定高度的势垒,这些势垒能阻挡低能载流子的输运,提高输运载流子平均能量、减少输运载流子浓度,从而提高Seebeck系数和功率因子、降低电子热导率,实现热电优值ZT的显著增加。本文简要介绍势垒过滤机制,综述势垒过滤优化热电性能的理论和实验研究进展,确定最优势垒高度是应用势垒过滤机制的基础,探索晶界或纳米复合相形成势垒的调控方法是未来研究的重要方向。

     

    Abstract: A potential barrier will be created due to various kinds of interface and defects existed in the material, which would lead to the impeding of the low energy carrier's transport, resulting in higher average carrier energy and lower active carrier density. This carrier filtering effects would cause the improvement of Seebeck coefficient and power factor with simultaneously decreasing of carriers thermal conductivity, and finally bring dramatically increasing of the thermoelectric figure-of-merit ZT. This paper briefly introduced the potential barrier filtering, and reviewed the progressing of this mechanism on theory and laboratory research. Based on these progressing, we proposed that the optimal barrier height should be determined first for this mechanism, and the tuning method of the barrier height aroused from the interfaces between the nano composites and the matrix material, or the grain boundaries, should be fully explored in future.

     

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